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Synthesis and stereochemistry of mono- and di-olefin derivatives of tetrairidium carbonyl clusters

โœ Scribed by Renzo Ros; Alberto Scrivanti; Raymond Roulet


Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
669 KB
Volume
303
Category
Article
ISSN
0022-328X

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AS part of an lnvestlgatlon of the iron carbonyl catalysed lsomerlsatlon of allyllc alcohols1'2'3 , Cowherd and van Rosenberg' showed that, whereas the trlcycllc alcohol (1, D = H) lsomerlsed to the ketone (2, D = H) on heating In the presence of iron pentacarbonyl, its eplmer did not react under sl