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Stereochemistry and mechanism of iron carbonyl induced olefin isomerisation in allylic alcohols

✍ Scribed by J.U. Strauss; P.W. Ford

Publisher: Elsevier Science
Year: 1975
Tongue: French
Weight: 94 KB
Volume: 16
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)75030-1

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✦ Synopsis

AS part of an lnvestlgatlon of the iron carbonyl catalysed lsomerlsatlon of allyllc alcohols1'2'3 , Cowherd and van Rosenberg' showed that, whereas the trlcycllc alcohol (1, D = H) lsomerlsed to the ketone (2, D = H) on heating In the presence of iron pentacarbonyl, its eplmer did not react under slrmlar condltlons.

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