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Synthesis and stereochemical assignment of trans-2-methyl-2-pentenoic acid and the corresponding esters, aldehydes, and alcohols

โœ Scribed by Chan, Kai C.; Jewell, Richard A.; Nutting, William H.; Rapoport, Henry

Book ID
121417394
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
573 KB
Volume
33
Category
Article
ISSN
0022-3263

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Diastereoselective synthesis of erythro-
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โœ Toshio Sato; Kazuhisa Tajima; Tamotsu Fujisawa ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 148 KB

The ester enolate Claisen rearrangement of IE)-and IZ)-2-butenyl ## 2-hydroxyacetates gave erythro-and threo-2-hydroxy-3-methyl-4-pentenoic acids with high diastereoselectivity via silyl ketene acetals, respect<vely.