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Synthesis and spectroscopy of nickel(II) complexes with 5-methyl-3-formylpyrazoleN(4)-methyl-N(4)-cyclohexyl thiosemicarbazone (HMPz4MCy): X-ray crystal structure of [Ni(HMPz4MCy)2]Cl2·2.5H2O

✍ Scribed by Dhiman Kumar Sau; Nityananda Saha; Ray J. Butcher; Siddhartha Chaudhuri


Book ID
111613518
Publisher
Springer
Year
2004
Tongue
English
Weight
240 KB
Volume
29
Category
Article
ISSN
0340-4285

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## Abstract [Bu~4~N][Ni(mdt)~2~] (H~2~mdt = 2__H__‐1,3‐dithiole‐4,5‐dithiol) has been prepared in a three‐step synthesis from [Bu~4~N]~2~[Zn(dmit)~2~] (H~2~dmit = 2‐thione‐1,3‐dithiole‐4,5‐dithiol). The crystal structure is reported which shows that the Ni(mdt)~2~ anion is distorted significantly f