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Synthesis and spectroscopic characterisation of tritelluroether, triselenoether, and trithioether complexes of Cr(0), Mo(0) and W(0)

✍ Scribed by Andrew J Barton; Julie Connolly; William Levason; Arantza Mendia-Jalon; Simon D Orchard; Gillian Reid


Book ID
108427932
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
92 KB
Volume
19
Category
Article
ISSN
0277-5387

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## Abstract (1‐^13^C)‐, (2‐^13^C)‐, (3‐^13^C)‐, (3‐^13^CH~3~)‐, (4‐^13^C), and (^13^CH~3~O)~2~‐ ubiquinone‐10 and the corresponding (1‐^13^C)‐, (6‐^13^C)‐, (5‐^13^C)‐, (5‐^13^CH~3~)‐, (4‐^13^C)‐, and (^13^CH~3~O)~2~‐ubiquinone‐0 have been synthesised from simple labelled starting materials via a si

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The complex chemical behaviour of 2-phosphaindolizines 1 strong upfield signal (Ξ΄ 31 P = 6.1) was observed with a coordination shift of βˆ†Ξ΄ = -161.7, which is typical for Ο€-(1,3-azaphospholo[1,5-a]pyridines) towards metal carbonyl compounds was studied. (Ξ· 1 -2-Phosphaindolizine)M(CO) 5 coordination.