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Synthesis and spectral characterization of cyclotriphosphazene based 18-membered macrocycles

✍ Scribed by Pakkirisamy Thilagar; Pagidi Sudhakar; P. Chinna Ayya Swamy; Sanjoy Mukherjee

Book ID
113642561
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
317 KB
Volume
390
Category
Article
ISSN
0020-1693

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Metal phthalocyanines (M = Cu, Ni, Co, SnCI2) 3-6 containing four 14-membered tetraaza macrocycles have been prepared. Detosylation of the aza functions has provided donor sites for binding four Ni2+ ions giving a pentanuclear com-plex which is extremely soluble in polar solvents. The mass spectrum