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Synthesis and some transformations of halogen-substituted o-quinones in the benzofuran series

โœ Scribed by A. N. Grinev; N. V. Arkhangel'skaya; G. Ya. Uretskaya; T. F. Vlasova

Book ID
112448331
Publisher
Springer US
Year
1975
Tongue
English
Weight
276 KB
Volume
11
Category
Article
ISSN
0009-3122

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Substitued N-(isoxazol-4-yl)thioureas 1 undergo a transformation in the presence of hexacarbonylmolybdenum and acid to yield functionalized thiazoles 3 in a one-pot reaction. In a few cases, 1,4,5-trisubstituted dihydroimidazoleth,iones 4 are also isolated as side products. Mechanistic consideration