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Synthesis and solution structure of heterobimetallic rhenium-iridium polyhydride complexes

✍ Scribed by Michos, Demetrius; Luo, Xiao Liang; Crabtree, Robert H.


Book ID
127365293
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
610 KB
Volume
32
Category
Article
ISSN
0020-1669

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New organoplatinum-rhenium heterobimetallic complexes (organic ligand = Me (1), Et (2), CH2Ph (3), Ph (4)) with sulfur ligands have been prepared and characterized by IR, IH and 13c{1n} NMR, elemental analysis, and chemical reactions. Complex 1 was thermally more stable than related PtMeCi(cod) (5)