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Synthesis and molecular structures of diorganophosphido-bridged heterobimetallic complexes

✍ Scribed by Baker, R. T.; Tulip, T. H.; Wreford, S. S.

Book ID
127025578
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
587 KB
Volume
24
Category
Article
ISSN
0020-1669

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## 495 [El][BF 4 ] or [El][OSO 2 CF 3 ] (El = H, Me). The dppa backbone of 4 is readily deprotonated by KOSiMe 3 to yield the very stable zwitterionic aminocarbyne complex [(OC) 3 Fe{Β΅-CN(Me)2,6-xylyl}(Β΅-Ph 2 PNPPh 2 )Pt(PPh 3 )] 5.