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Synthesis and Solid-State Structure of Zn(η 5 -C 5 Me 4 SiMe 3 )(η 1 -C 5 Me 4 SiMe 3 ), a Zincocene with Nonparallel Cyclopentadienyl Rings

✍ Scribed by Fernández, Rafael; Resa, Irene; del Río, Diego; Carmona, Ernesto; Gutiérrez-Puebla, Enrique; Monge, Ángeles

Book ID
126236269
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
104 KB
Volume
22
Category
Article
ISSN
0276-7333

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Activation of the (Trimethylsilyl)tetram
Activation of the (Trimethylsilyl)tetramethylcyclopentadienyl Ligand in the [C 5 Me 4 (SiMe 3 )] 2 TiCl 2 /Mg System, Yielding Intramolecular Si−CH 2 −Mg and Si−CH 2 −Ti Bonds. Molecular Structures of {[η 5 -C 5 Me 4 SiMe 2 (μ-CH 2 { Mg , Mg })][η 5 -C 5 Me 4 (SiMe 3 )]Ti III (μ-H) 2 Mg(THF)} 2 and [η 5 :η 1 -C 5 Me 4 SiMe 2 CH 2 ][η 5 -C 5 Me 4 (SiMe 3 )]Ti III
✍ Horáček, Michal; Hiller, Jörg; Thewalt, Ulf; Polášek, Miroslav; Mach, Karel 📂 Article 📅 1997 🏛 American Chemical Society 🌐 English ⚖ 215 KB