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Synthesis and Selected Reactions of a Bicyclic Sultam Having Sulfur at the Apex Position

โœ Scribed by Preston, Adam J.; Gallucci, Judith C.; Paquette, Leo A.


Book ID
127074453
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
128 KB
Volume
71
Category
Article
ISSN
0022-3263

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Synthesis of chiral allyltitaniums havin
โœ Xin Teng; Aleksandr Kasatkin; Yasufumi Kawanaka; Sentaro Okamoto; Fumie Sato ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 244 KB

Chiral allyltitaniums having an amino substituent at the C-4 position are prepared from optically active allylic alcohol derivatives I and a Ti(O-i-Pr)4/2i-PrMgCl reagent, which, in turn, react with aldehydes regio-and stereoselectively to afford 3-amino-2-vinylalkanols in excellent yields.