𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis and reduction of thieno[2′,3′(3′,2′ or 3′,4′):5,6]-azocino[2,1-a]isoindole-7, 13-diones

✍ Scribed by Mohamed Othman; Pascal Pigeon; Bernard Decroix

Publisher
Journal of Heterocyclic Chemistry
Year
1998
Tongue
English
Weight
353 KB
Volume
35
Category
Article
ISSN
0022-152X

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

A synthesis of the thieno[2′,3′(3′,2′ or 3′,4′):5,6]azocino[2,1‐a]isoindole‐7,13‐diones 6a‐c was developed from N‐thienylethylphthalimides 3a‐c using a Wittig reaction followed by a Friedel‐Crafts cyclization of acetic acid derivatives 5a‐c. Reduction of ketones 6a‐c into alcohols 7a‐c was stereo specific.

📜 SIMILAR VOLUMES

4,5,7-Trichloro-6-(2,4-dimethylthiazol-5
4,5,7-Trichloro-6-(2,4-dimethylthiazol-5-yl)-2-(3-hydroxypropyl)isoindole-1,3-dione
✍ Fun, Hoong-Kun ;Ng, Shea-Lin ;Ye, Miao ;Xu, Jian-Hua 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 313 KB

In the title compound, C 16 H 13 Cl 3 N 2 O 3 S, the 1,3-thiazole ring is almost orthogonal to the isoindoline plane, making a dihedral angle of 89.74 (9) . Intermolecular O-HÁ Á ÁN and C-HÁ Á ÁO interactions and SÁ Á ÁO short contacts link the molecules into a three-dimensional framework. The cryst

Tetracyclic systems: Synthesis of isoind
Tetracyclic systems: Synthesis of isoindolo[1,2-b]thieno-[2,3(3,2 or 3,4)-e][1,3]thiazocines and Isoindolo[2,1-a]thieno-[2,3(3,2 or 3,4)-f][1,4] and [1,5]diazocines
✍ Pascal Pigeon; Bernard Decroix 📂 Article 📅 1997 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 432 KB 👁 1 views

## Abstract Cyclization of thioglycolic acids derivatives 3a‐d gave isoindolo[1,2‐__b__]thieno[2,3(3,2 or 3,4)‐__e__][1,3]‐thiazocines 4a‐d. Isoindolo[2,1‐__a__]thieno[2,3(3,2 or 3,4)‐__f__][1,4] or [1,5]diazocines 10b or 11a‐c were synthesized from Beckmann or Schmidt rearrangement of the ketones

Synthesis of new heteroaromatic nitrogen
Synthesis of new heteroaromatic nitrogen ligands: Pyrimido-[4″,5″:4′,5′]-thieno[3′,2′:4,5]thieno[3,2-d]pyrimidines and 1,2,3-triazine[4″,5″:4′,5′]thieno[3′,2′:4,5]thieno[3,2-d]-1,2,3-triazines
✍ Gerardo Blanco; José M. Quintela; Carlos Peinador 📂 Article 📅 2006 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 126 KB 👁 1 views

## Abstract magnified image An efficient one‐pot access for the synthesis of the previously unreported tetracyclic fused pyrimido‐[4″,5″:4′,5′]thieno[3′,2′:4,5]thieno[3,2‐__d__]pyrimidine (**3**) and 1,2,3‐triazine[4″,5″:4′,5′]thieno‐[3′,2′:4,5]thieno‐[3,2‐__d__]‐1,2,3‐triazine (**5**) heteroaroma