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Synthesis and rearrangement of some 4,5-disubstituted homocubyl derivatives

โœ Scribed by R.D. Miller; D. Dolce

Book ID
104245443
Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
200 KB
Volume
13
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

A recent report by Zwanenburg and Rlunder' concerning the synthesis and reactions of the bridgehead substituted homocubyl alcohol derivative, 1, prompts us to report our efforts to prepare some reactively functionalized 4,5-dieubstituted homocubyl derivatives, 2. These compound8 ware desired for a study of their chemical, pyrolytic, and transition metalcatalyzed rearrangements. Additionally, the unique 4,5-functionalization was considered essential for activation of the central bond for subsequent transformation into derivativee containing the unknown tetracyclo[4.3.0.03'g,04'7 ] skeleton for a study of the chemical and

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Bis-homoketonization of some 4,5-disubst
Bis-homoketonization of some 4,5-disubstituted homocubyl derivatives
โœ R.D. Miller; D. Dolce ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 206 KB

There are presently a number of examples of homoketonization reported in the literature. 1 Our current interest in strained, unenolizable a-diketones led to the investigation of the pheno. menon of bis-homoketonization of certain vicinal dials, where the alcohol functionality is situated at strain