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Bis-homoketonization of some 4,5-disubstituted homocubyl derivatives

โœ Scribed by R.D. Miller; D. Dolce

Book ID
104246744
Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
206 KB
Volume
14
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

There are presently a number of examples of homoketonization reported in the literature. 1

Our current interest in strained, unenolizable a-diketones led to the investigation of the pheno.

menon of bis-homoketonization of certain vicinal dials, where the alcohol functionality is situated at strained ring junctures, as potential synthetic sources of interesting s-diketones.

Our preliminary results on 4,5-dihydroxypentacyclo [4.3.0.02'5.03y8.04'7] nonane, l&, are described.in this communic.,.ion.

๐Ÿ“œ SIMILAR VOLUMES

Synthesis and rearrangement of some 4,5-
Synthesis and rearrangement of some 4,5-disubstituted homocubyl derivatives
โœ R.D. Miller; D. Dolce ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 200 KB

A recent report by Zwanenburg and Rlunder' concerning the synthesis and reactions of the bridgehead substituted homocubyl alcohol derivative, 1, prompts us to report our efforts to prepare some reactively functionalized 4,5-dieubstituted homocubyl derivatives, 2. These compound8 ware desired for a s