Synthesis and Rearrangement of Cyclohexadienones
โ Scribed by Woodward, R. B.; Singh, Tara
- Book ID
- 115472758
- Publisher
- American Chemical Society
- Year
- 1950
- Tongue
- English
- Weight
- 740 KB
- Volume
- 72
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Low temperature addition of functionalized alkyllithium reagents to p-benzoquinones produces 4-alkyl-4-hydroxycyclohexa-2,5-dienones, and reaction of excess of the reagents with quinones yields 1,4-dialkylcyclohexa-2,5-diene-1,4-diols. With 4-acetoxy-, 4hydroxy-, and 4-methoxy-4lnethylcyclohexa-2,5
The Few-doped acidic KlO clay accelerates greatly, by factors of 105-106, tbetitle reaction. These rearrangements thus occur in a fewminutes atrocnntenperature, according to [1,21 and [3,31 pathways. FACIIE s-try-allowed pericyclic reactions --such as Diels-Alder cycloadditions, Claisen andCoperearr