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A new photochemical rearrangement of 2,4-cyclohexadienones

โœ Scribed by Harold Hart; A.J. Waring


Book ID
104236110
Publisher
Elsevier Science
Year
1965
Tongue
French
Weight
149 KB
Volume
6
Category
Article
ISSN
0040-4039

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IT is well established that 4-ntethylcyclohexadienones of the santonin type undergo photochemical transformation in aqueous acetic acid to perhydroasulene derivatives of the isophotosantonic la&one type.' The photochemical properties of cyclohexadienones which are unsubstituted at C4 have also been

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The oxidation of salicylalcohol (I; R=R'=H) by sodium periodate was recently reported to give a dehydrodimer by spontaneous Diels-Alder reaction of the intermediary Spiro-epoxy-2,4-cyclohexadienone II (R=R'=H). Analogous