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Oxidative formation and photochemical isomerization of spiro-epoxy-2,4-cyclohexadienones

✍ Scribed by Hans-Dieter Becker; Torbjorn Bremholt; Erich Adler

Book ID: 104245357
Publisher: Elsevier Science
Year: 1972
Tongue: French
Weight: 176 KB
Volume: 13
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)94276-5

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✦ Synopsis

The oxidation of salicylalcohol (I; R=R'=H) by sodium periodate was recently reported to give a dehydrodimer by spontaneous Diels-Alder reaction of the intermediary Spiro-epoxy-2,4-cyclohexadienone II (R=R'=H). Analogous

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