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Synthesis and Reactivity of the Osmate(0) Complexes M[Os(CO)2(.eta.-C5R5)] (M = Li, Na; R = H, Me): Versatile Synthons for Synthesis of Organoosmium Complexes

✍ Scribed by Kawano, Yasuro; Tobita, Hiromi; Ogino, Hiroshi


Book ID
126929460
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
538 KB
Volume
13
Category
Article
ISSN
0276-7333

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## Abstract Reaction of [(Ξ·^5^‐C~5~H~5~)(CO)~2~M=P=C(SiMe~3~)~2~] [where M = Mo (2), W (5)] with the phosphaalkene __t__BuP=C(NMe~2~)~2~ (1a) afforded the Ξ·^3^‐1,2‐diphosphaallyl complexes [(Ξ·^5^‐C~5~H~5~)(CO)~2~M{Ξ·^3^‐__t__BuPPC(SiMe~3~)~2~}], [where M = Mo (3a); M = W (6)]. Similarly, 2 and CyP=C