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The formation and synthetic applications of new acetonitrile derivatives of cycloheptatrienyl-molybdenum and -tungsten complexes; synthesis of binuclear [M(CO)3(η-C5R5)M(CO)2(η-C7H7)] (M = Mo, R = H or Me; M = W, R = H)

✍ Scribed by Roy Breeze; Allen Ricalton; Mark W. Whiteley

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
286 KB
Volume
327
Category
Article
ISSN
0022-328X

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## Abstract Reaction of [(η^5^‐C~5~H~5~)(CO)~2~M=P=C(SiMe~3~)~2~] [where M = Mo (2), W (5)] with the phosphaalkene __t__BuP=C(NMe~2~)~2~ (1a) afforded the η^3^‐1,2‐diphosphaallyl complexes [(η^5^‐C~5~H~5~)(CO)~2~M{η^3^‐__t__BuPPC(SiMe~3~)~2~}], [where M = Mo (3a); M = W (6)]. Similarly, 2 and CyP=C