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Synthesis and Reactivity of Ruthenium Azido Complexes Containing a Hydridotris(pyrazolyl)borate Ligand and Dimerization of Terminal Alkynes in Organic and Aqueous Media

✍ Scribed by Chen, Chien-Kai; Tong, Hung-Chun; Chen Hsu, Chih-Yung; Lee, Chia-Yi; Fong, Yih Hsuan; Chuang, Yao-Shun; Lo, Yih-Hsing; Lin, Ying-Chih; Wang, Yu

Book ID: 125899932
Publisher: American Chemical Society
Year: 2009
Tongue: English
Weight: 252 KB
Volume: 28
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om800952t

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## Abstract The water‐soluble complexes [RuCl~2~(η^6^‐__p__‐cymene){__κ__‐(__P__)‐PPh~3n~(OCH~2~CH~2~NMe~3~)~n~}][SbF~6~]~n~ [n=1 (4a), 2 (4b) or 3 (4c)] have been prepared from the neutral precursors [RuCl~2~(η^6^‐__p__‐cymene){__κ__‐(__P__)‐PPh~3‐n~(OCH~2~CH~2~NMe~2~)~n~}] [n=1 (2a), 2 (2b) or 3