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Synthesis and reactivity of polymetallated olefins and functionalized metalloalkynes

✍ Scribed by Julia Kaftanov; Claudia Averbuj; Natalia Vais-Morlender; Annie Liard; Ilan Marek

Book ID
104323685
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
128 KB
Volume
19
Category
Article
ISSN
0277-5387

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✦ Synopsis

The first straightforward synthesis of tris-metallated olefins and functionalized metallated alkynes is reported via the use of low-valent titanium derivatives.

πŸ“œ SIMILAR VOLUMES

Diamination of Olefins: Synthesis, Struc
Diamination of Olefins: Synthesis, Structures and Reactivity of Osmaimidazolidines
✍ Kilian MuΓ±iz; Atsushi Iesato; Martin Nieger πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 412 KB πŸ‘ 2 views

## Abstract The diamination of certain olefins bearing electron‐withdrawing substituents proceeds with well‐defined bisimido and trisimido complexes of osmium. The products are obtained as osmaimidazolidines which are of unprecedented stability with regards to olefin functionalisation. Osmium compl