Synthesis and reactivity of pelletierine-derived building blocks and pelletierine analogs
✍ Scribed by Lok-Hang Yan; Flore Dagorn; Edmond Gravel; Blandine Séon-Méniel; Erwan Poupon
- Book ID
- 116909494
- Publisher
- Elsevier Science
- Year
- 2012
- Tongue
- French
- Weight
- 922 KB
- Volume
- 68
- Category
- Article
- ISSN
- 0040-4020
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## Abstract The synthesis is described of (‐)‐pelletierine picrate identical with __Tanret's__ pelletierine picrate from __Punica granatum__ L. and of its antipode by oxidation, respectively, of (‐)‐ and of (+)‐sedridine. The sedridines are alkaloids with known absolute configuration of the piperid
## Abstract As a contribution to bioorganometallic chemistry, a dia‐ and enantioselective synthesis of novel carbocyclic amino acid analogues with a 1,2‐ferroceno‐fused cyclopentene backbone has been developed. Using two related planar‐chiral intermediates, i.e. (1__S__,__E__)‐ethyl‐3‐[2‐(phenylsul