✦ LIBER ✦

Synthesis and absolute configuration of Tanret's (-)-pelletierine

✍ Scribed by H. C. Beyerman; L. Maat

Book ID: 104586697
Publisher: Elsevier Science
Year: 2010
Tongue: English
Weight: 379 KB
Volume: 82
Category: Article
ISSN: 0165-0513
DOI: 10.1002/recl.19630821012

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✦ Synopsis

Abstract

The synthesis is described of (‐)‐pelletierine picrate identical with Tanret's pelletierine picrate from Punica granatum L. and of its antipode by oxidation, respectively, of (‐)‐ and of (+)‐sedridine. The sedridines are alkaloids with known absolute configuration of the piperidine asymmetric carbon atom. From this follows the D~s~‐configuration of (‐)‐pelletierine.

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