Synthesis and Reactivity of Metal Complexes with the Zwitterionic Et3PCS2 Ligand. X-Ray Structure of the Dithiocarbonate Complex [(triphos) CoS2CO]
โ Scribed by Dr. Claudio Bianchini; Dr. Andrea Meli; Dr. Annabella Orlandini
- Publisher
- John Wiley and Sons
- Year
- 1982
- Tongue
- English
- Weight
- 150 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
V= 1246.97 A', ecalc= 1.311 g . ~r n -~. From 3154 measured reflections (MoK, radiation, h = 0.71073 A) 2128 with I>2u(Z) were used for the refinement of the structure [R(F) [ "I This work was supported by the Deutsche Forschungsgemeinschaft, the Fonds der Chemischen Industrie and BASF AG. Ludwiasha
Quantum mechanical ab initio calculations at the MP2 and CCSD(T) level of theory have been used to investigate the geometries and bond energies of the complexes M(CO) 6ยฑx (H 2 ) x (M = Cr, Mo, W; x = 1, 2, 3). The theoretically predicted M(CO) 5 ยฑ(H 2 ) bond dissociation energies are in excellent ag