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Synthesis and reactivity of extremely thermally stable trialkylpalladium(IV) complexes supported with 1,4,7-triazacyclononane

✍ Scribed by Anton A. Sobanov; Andrei N. Vedernikov; Gerald Dyker; Boris N. Solomonov


Book ID
111730316
Publisher
Royal Society of Chemistry
Year
2002
Tongue
English
Weight
81 KB
Volume
12
Category
Article
ISSN
0959-9436

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The complexation of iron(iii) chloride with 1,4,7-tris[3,4-bis(decyloxy)benzyl]-1,4,7-triazacyclononane leads to a liquid crystalline product, which forms a second mesophase after thermal treatment at around 70 8C above the first clearing temperature. Polarizing microscopy, DSC, and UV observations