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Dinuclear 1,4,7-triazacyclononane (tacn) complexes of cobalt(iii) with amido and tacn bridges. Synthesis, characterization and reversible acid-accelerated bridge cleavage

✍ Scribed by Andersen, Peter; Glerup, Jørgen; Gumm, Andreas; Hansen, Solveig Kallesøe; Magnussen, Magnus


Book ID
121240258
Publisher
Royal Society of Chemistry
Year
2004
Tongue
English
Weight
395 KB
Volume
18
Category
Article
ISSN
1477-9226

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The complexation of iron(iii) chloride with 1,4,7-tris[3,4-bis(decyloxy)benzyl]-1,4,7-triazacyclononane leads to a liquid crystalline product, which forms a second mesophase after thermal treatment at around 70 8C above the first clearing temperature. Polarizing microscopy, DSC, and UV observations