Synthesis and Reactivity of a ( μ -1,1-Hydroperoxo)( μ -hydroxo)dicopper(II) Complex: Ligand Hydroxylation by a Bridging Hydroperoxo Ligand
✍ Scribed by Itoh, Kyosuke; Hayashi, Hideki; Furutachi, Hideki; Matsumoto, Takahiro; Nagatomo, Shigenori; Tosha, Takehiko; Terada, Shoichi; Fujinami, Shuhei; Suzuki, Masatatsu; Kitagawa, Teizo
- Book ID
- 121419429
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 375 KB
- Volume
- 127
- Category
- Article
- ISSN
- 0002-7863
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## Abstract The copper coordination chemistry of a new imidazolidine‐based doubly bridging μ‐bis(tetradentate) ligand, H~3~mhbai is studied. A new family of pentacoordinate dinuclear complexes of formula [Cu^II^~2~(‐mhbai)(‐X)]·2 H~2~O (1–4) [X = OAc, NO~3~, Cl, S~2~COMe], where H~3~mhbai stands fo
## Abstract Three azido‐bridged Mn^II^ complexes of formulas [Mn~2~(N~3~)~4~(ttp)~2~] (1), [Mn~2~(N~3~)~4~(ttp‐N~3~)~2~] (2) and [Mn~2~(N~3~)~4~(ttp‐N~3~)~2~]~3~[Mn^III^(ttp‐N~3~)(N~3~)~3~]~2~ (3), where ttp and ttp‐N~3~ represent 4′‐__p__‐tolyl‐2,2′:6′,2″‐terpyridine and 4′‐__p__‐azidomethylphenyl