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Synthesis and reactions of unsaturated sugars. XI. Evidence for a carbenoid intermediate in the Corey-Winter alkene synthesis

✍ Scribed by Horton, Derek.; Tindall, Charles G.


Book ID
121076800
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
287 KB
Volume
35
Category
Article
ISSN
0022-3263

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Synthesis and Hydrolysis of [Alkenyl(alk
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A variety of alkenylcarbene complexes [CpЈ(CO) 2 Mn= with water affords the α,β-unsaturated aldehyde complexes [CpЈ(CO) 2 Mn(η 2 -RCH=CHCHO] (5), from which the C(OEt)CH=CHR] (3) (CpЈ = η 5 -MeC 5 H 4 ) was obtained in a straightforward manner upon aldol condensation of aldehydes RC(H)=C(H)C(H)O (6)