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Synthesis and reactions of the first cyclopentadienyl isonitriles

✍ Scribed by Klaus Banert; Frank Köhler; Barbara Meier

Book ID
104253554
Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
109 KB
Volume
44
Category
Article
ISSN
0040-4039

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✦ Synopsis

Azidofulvenes without a further substituent in the exocyclic position were transformed into new 1-isocyano-and 2-isocyanocyclopenta-1,3-dienes by photolysis in methanol. These novel functionalized cyclopentadienes are useful building blocks, e.g. as dienes in Diels-Alder reactions.

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