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Passerini and Ugi reactions of anomeric glucosyl isonitriles

✍ Scribed by Thomas Ziegler; Rolf Schlömer; Christoph Koch


Book ID
104259642
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
198 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis


Acetyl and benzyl protected 13-D-glucopyranosyl isonitriles were treated with various aldehydes and acetic acid to give the corresponding Passerini reaction products and with i-butanal, carboxylic acids and amines to give the corresponding Ugi reaction products, respectively. No significant diastereoselectivity was observed for both reactions.


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Passerini and Ugi reactions of benzyl an
✍ Thomas Ziegler; Hans-Josef Kaisers; Rolf Schlömer; Christoph Koch 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 731 KB

Acetyl and benzyl protected anomeric [~-D-glucopyrunosyl isonitriles and 1,3,4,6-tetra-Oacetyl-2-dcoxy-2-isocyano-13-D-glucopyranose were treated with various carbonyl compounds and, carboxylic acids to give the corresponding Passerini reaction products and with i-butanal, carboxylic acids and amine