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Synthesis and reactions of silicon containing cyclic α-amino acid derivatives

✍ Scribed by Sambasivarao Kotha; Enugurthi Brahmachary


Book ID
108187759
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
220 KB
Volume
689
Category
Article
ISSN
0022-328X

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The electrophilic imino esters XF 2 CC(=NPG)CO 2 Me and imino phosphonates CF 3 CC(=NPG)P(O)(OR) 2 (PG = SO 2 Ph, Cbz, Boc) were transformed by nucleophilic and then electrophilic additions into fluorine-containing amino esters and amino phosphonates with two pendent alkene chains [Z = CO 2 Me, P(O