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Synthesis and reactions of lithio derivatives of 1-allenylbenzotriazole

โœ Scribed by Alan R. Katritzky; Sergei V. Verin

Book ID
112131164
Publisher
Journal of Heterocyclic Chemistry
Year
1995
Tongue
English
Weight
508 KB
Volume
32
Category
Article
ISSN
0022-152X

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The title compounds derived from 1, 1-dibromocyclopropanes are transformed into (1) cyclopropyltrimethylsilanes via 1-trimethylsilylcyclopropyllithium species, (2) 1-alkylidenecyclopropanes by the Peterson-olef=tion, and (3) 1-acetyl(or 1-allyl)cyclopropylsilanes with dibutylcopperlithium and acetyl