Synthesis and radical polymerization of vinyl monomers bearing penicillin skeleton: New chiral polymers and observation of complete polymerization inhibition
β Scribed by Yasushi Saotome; Takeo Miyazawa; Takeshi Endo
- Book ID
- 105336606
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1988
- Tongue
- English
- Weight
- 328 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0887-6258
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The radical polymerization of N-acryloyl-N-(p-tolylsulfonyl)urea ( 2), prepared easily by the reaction of p-toluenesulfonyl isocyanate with acrylamide, was carried out in DMF, DMSO, or NMP at 60ΠC by use of AIBN as an initiator to give a polymer 3 in a good yield. Copolymerization parameters of 2 we
New hybrid vinyl monomers with both cationic-and radical-polymerizable vinyl groups were synthesized by the reaction of bis[ l-(chloromethyl)-2-(vinyloxy)ethyl]terephthalate (3) with unsaturated carboxylic acids using 1,8-diazabicyclo[5.4.0] -undecene-7 (DBU) as a base. The reaction of 3 with methac