Kinetic Modeling of Hyperbranched Polymer Synthesis through Atom-Transfer and Nitroxide-Mediated Radical Polymerization of Vinyl/Divinyl Monomers

Synthesis of a functional polymer with p

Synthesis of a functional polymer with pendent luminescent phenylenevinylene units through nitroxide-mediated free-radical polymerization

✍ Marc Moroni; Alain Hilberer; Georges Hadziioannou 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 480 KB

## Abstract In this communication we report the synthesis and the efficient polymerization of a PPV trimer, 4‐__tert__‐buty1‐4′‐(4‐vinylstyryl)‐__trans__‐stilbene. By using the TEMPO (2,2,6,6‐tetramethylpiperidin‐1‐yloxy)‐mediated free‐radical polymerization method, the corresponding polymer was ob