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Synthesis and radical polymerization of 2-(p-vinylbenzyl)dibenzothiophene

✍ Scribed by Osamu Shimomura; Toshihiko Sato; Ikuyoshi Tomita; Masato Suzuki; Takeshi Endo


Book ID
104425652
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
355 KB
Volume
40
Category
Article
ISSN
1381-5148

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## Abstract Some hindered amine polymers containing 2,2,6,6‐tetramethylpiperidine structure were synthesized. A new monomer, 4‐O‐vinylbenzyl‐2,2,6,6‐tetramethylpiperidine, was homopolymerized and copolymerized with some vinyl monomers in the presence of AIBN as an initiator. The obtained amine poly

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A monomer having dibenzothiophene moiety, 2-vinyldibenzothiophene (1), was prepared by the Ni-catalyzed cross-coupling reaction of vinyl bromide with the Grignard reagent of 2-bromodibenzothiophene. The radical homopolymerization of 1 and the copolymerization with styrene were carried out at 60ЊC in