Synthesis and polymerization of 4-o-vinylbenzyl-2,2,6,6-tetramethylpiperidine
β Scribed by Miyazawa, Takeo ;Endo, Takeshi ;Okawara, Makoto
- Publisher
- John Wiley and Sons
- Year
- 1985
- Weight
- 360 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0360-6376
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β¦ Synopsis
Abstract
Some hindered amine polymers containing 2,2,6,6βtetramethylpiperidine structure were synthesized. A new monomer, 4βOβvinylbenzylβ2,2,6,6βtetramethylpiperidine, was homopolymerized and copolymerized with some vinyl monomers in the presence of AIBN as an initiator. The obtained amine polymers were oxidized with hydrogen peroxide to obtain the polymers having nitroxyl radical moiety.
π SIMILAR VOLUMES
Radical polymerization of 2-, 3-, and 4-chlorostyrenes (ClSts) was investigated with benzoyl peroxide (BPO) as an initiator, in the presence of 4-methoxy-2,2,6,6tetramethylpiperidine-1-oxyl (MTEMPO). The polymerization was performed in bulk for 3.5 h at 95ΠC and then continued for a defined time at