𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis and polymerization of 4-o-vinylbenzyl-2,2,6,6-tetramethylpiperidine

✍ Scribed by Miyazawa, Takeo ;Endo, Takeshi ;Okawara, Makoto


Publisher
John Wiley and Sons
Year
1985
Weight
360 KB
Volume
23
Category
Article
ISSN
0360-6376

No coin nor oath required. For personal study only.

✦ Synopsis


Abstract

Some hindered amine polymers containing 2,2,6,6‐tetramethylpiperidine structure were synthesized. A new monomer, 4‐O‐vinylbenzyl‐2,2,6,6‐tetramethylpiperidine, was homopolymerized and copolymerized with some vinyl monomers in the presence of AIBN as an initiator. The obtained amine polymers were oxidized with hydrogen peroxide to obtain the polymers having nitroxyl radical moiety.


πŸ“œ SIMILAR VOLUMES


Synthesis of well-defined polychlorostyr
✍ Eri Yoshida; Takamasa Fujii πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 154 KB πŸ‘ 2 views

Radical polymerization of 2-, 3-, and 4-chlorostyrenes (ClSts) was investigated with benzoyl peroxide (BPO) as an initiator, in the presence of 4-methoxy-2,2,6,6tetramethylpiperidine-1-oxyl (MTEMPO). The polymerization was performed in bulk for 3.5 h at 95ЊC and then continued for a defined time at