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Synthesis and radical copolymerization of new type pyridinum monomer and redox behavior of its polymers

✍ Scribed by Naoya Kitamura; Yoko Nambu; Takeshi Endo

Book ID: 105337440
Publisher: John Wiley and Sons
Year: 1990
Tongue: English
Weight: 324 KB
Volume: 28
Category: Article
ISSN: 0887-624X
DOI: 10.1002/pola.1990.080280210

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

A new type pyridinium salt monomer, 1‐vinyl‐4‐carbamidopyridinium perchlorate, was prepared, and then homopolymerized and copolymerized with methyl methacrylate (MMA), 2‐hydroxyethyl methacrylate (HEMA), styrene, and acrylonitrile. Redox potentials of these pyridinium salt monomer and polymers were more positive than that of the model compound (1‐methyl‐4‐carbamidopyridinium salt). The copolymer with MMA showed an interesting redox behavior.

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