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Synthesis and Pyrolysis of 3-Azaquadricyclane Derivatives. – A New Azepine Synthesis

✍ Scribed by Prof. Dr. H. Prinzbach; Dipl.-Chem. R. Fuchs; Dr. R. Kitzing


Publisher
John Wiley and Sons
Year
1968
Tongue
English
Weight
234 KB
Volume
7
Category
Article
ISSN
0044-8249

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Dibenz[b,f]azepines, Part 7[1]: Synthesi
✍ Ferenc Haász; Zoltán Tóth; Vilmos Galamb 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 315 KB

Reactions of 5-carboxamido-5H-dibenz[bflazepines (la-ld) with glyoxylic acid methylester methyl hemiacetal (GMHA) led to 5-(carboxamido-N-a-hydroxy-acetic acid methyl ester)-5Hdibenz[b,Aazepines (2a-2d). The reactions with glycols yielded the oligoethylene glycol derivatives (3,4). The new compounds