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Synthesis and Properties of (Tetra-tert-butylphthalocyaninato)ruthenium(II) and (Tetra-tert-butyl-2,3-naphthalocyaninato)ruthenium(II)

✍ Scribed by Hanack, Michael ;Knecht, Siegfried ;Polley, Rainer


Publisher
Wiley (John Wiley & Sons)
Year
1995
Tongue
English
Weight
559 KB
Volume
128
Category
Article
ISSN
0009-2940

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✦ Synopsis


The first synthesis of pure tert-butyl-substituted (phthalocy-3-chloropyridine, ammonia) is described. The compounds aninato)-and (2,3-naphthalocyaninato)ruthenium [ ( ~B u ) ~-were characterized by UV/Vis, IR, and NMR measurements. MacRu] by thermal decomposition of (tBu)4MacRu(L)2 (L =


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Synthesis, properties and crystal struct
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Tetra(n-butyl)ammonium nitrite reacts with β€˜dichlorophthalocyaninatoruthenium(III) acid’ to yield bis(tetra(n-butyl)ammonium) bisnitrophthalocyaninatoruthenate(II). It crystallizes monoclinic with crystal data: a = 15.114(4) Γ…, b = 22.34(3) Γ…, c = 18.206 (11) Γ…, Ξ² = 90.88(5)Β°; space group P1 21/n 1,