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Synthesis, properties and crystal structure of bis(tetra(n-butyl)ammonium) bisnitrophthalocyaninatoruthenate(II)

✍ Scribed by Svend Sievertsen; Morten Weidemann; Heiner Hückstädt; Heiner Homborg

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
147 KB
Volume
01
Category
Article
ISSN
1088-4246

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✦ Synopsis

Tetra(n-butyl)ammonium nitrite reacts with ‘dichlorophthalocyaninatoruthenium(III) acid’ to yield bis(tetra(n-butyl)ammonium) bisnitrophthalocyaninatoruthenate(II). It crystallizes monoclinic with crystal data: a = 15.114(4) Å, b = 22.34(3) Å, c = 18.206 (11) Å, β = 90.88(5)°; space group P1 21/n 1, Z = 4, and its X-ray crystal structure has been determined. Ru is located in the centre of the slightly distorted phthalocyaninate dianion, and is coordinated to two nitrite ions through their nitrogen (N) atoms in a staggered trans-configuration. The average Ru - N ~p~ ( Np pyrrolic N atoms) and Ru -N distance is 1.978(6) and 2.068(5) Å, respectively. The electrochemical and spectroscopic properties (IR, resonance Raman, UV/vis) of the compound are in full agreement with its molecular structure.

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