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Synthesis and Properties of Optically Active Phenoxypropionates. Effect of Halogeno Substituent in the Core on Physical Properties

✍ Scribed by Sugita, Shin-Ichi; Toda, Susumu; Yoshiyasu, Takashi; Teraji, Tsutomu

Book ID
115494848
Publisher
Taylor and Francis Group
Year
1993
Tongue
English
Weight
457 KB
Volume
237
Category
Article
ISSN
1058-725X

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Substituent effects on the physical prop
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✍ Kevin C. Gross; Paul G. Seybold πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 199 KB πŸ‘ 2 views

The aniline molecule is nonplanar, with its NH 2 group lying at an angle ΞΈ of approximately 42 β€’ to the plane of the benzene ring. Substituents on the phenyl ring alter this out-of-plane angle as well as other molecular properties such as the ring bond lengths and angles, the barrier to inversion E