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Effects of isocyanide substituents on the mesogenic properties of halogeno(isocyanide)gold complexes: calamitic and discotic liquid crystals

✍ Scribed by Coco, Silverio; Espinet, Pablo; Martín-Alvarez, José M.; Levelut, Anne-Marie


Book ID
120976746
Publisher
Royal Society of Chemistry
Year
1997
Tongue
English
Weight
285 KB
Volume
7
Category
Article
ISSN
0959-9428

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Treatment of the (isocyanide)gold(I) species LAuCl (L t BuNC, 2,6-Me 2 C 6 H 3 NC) with 4-mercaptobenzoic acid in the presence of NaOMe yields the complexes [Au(4-SC 6 H 4 CO 2 H)L] in good yield. Reaction of LAuCl with 2-HSQn (Qn quinoline) and 2-HSPy (Py pyridine) under the same conditions provide