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Synthesis and properties of [M6X12(C3H7NO)6]X2 (MNb, Ta; XCl, Br)

✍ Scribed by S. Širac; P. Planinić; Lj. Marić; N. Brničević; R.E. McCarley


Book ID
108328651
Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
468 KB
Volume
271
Category
Article
ISSN
0020-1693

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✍ I. Bašic; N. Brničević; U. Beck; A. Simon; R. E. McCarley 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 179 KB 👁 1 views

Compounds consisting of both cluster cations and cluster anions of the composition [(M 6 X 12 )(EtOH) 6 ][(Mo 6 Cl 8 )Cl 4 X 2 ] ´n EtOH ´m Et 2 O (M = Nb, Ta; X = Cl, Br) have been prepared by the reaction of (M 6 X 12 )X 2 ´6 EtOH with (Mo 6 Cl 8 )Cl 4 . IR data are given for three compounds. The