✦ LIBER ✦

Synthesis and properties of cyano-bridged nickel(II)-iron(III) complexes

✍ Scribed by Shuzhong Zhan; Xiaoyuan Chen; Qingjin Meng

Publisher: Springer
Year: 1996
Tongue: English
Weight: 246 KB
Volume: 21
Category: Article
ISSN: 0340-4285
DOI: 10.1007/bf00136552

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✦ Synopsis

Four kinds of novel CN-bridged Nin-Fe lu complexes, [NiL,(NC)Fe(CN)sI -, have been synthesized and characterized by elemental analysis, i.r. and u.v.-vis, spectral analysis, and magnetic moments. The formation of cyanide bridges is evident from the i.r. and u.v.-vis, spectra by the appearance of v(CN) shifts and changes in J~max with respect to the mononuclear parent complex [Fe(CN)6 ] 3 -. The magnetic properties indicate the existence of magnetic spin interactions between Ni H and Fe IH through the cyanide bridge.

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