Three new polynuclear Mn II complexes with chloroacetate bridges were obtained and characterized by X-ray diffraction: 2), and [Mn(µ-ClCH 2 COO) 2 (phen)] n (3). The Mn•••Mn distance for 1 (3.624 A ˚) is smaller than for 2 (4.613 A ˚) and 3 (4.530 A ˚); this is in agreement with the number of carbox
✦ LIBER ✦
Dinuclear and Polynuclear Bridged Azido–Nickel(II) Complexes: Synthesis, Structure Determination, and Magnetic Properties
✍ Scribed by Salah S. Massoud; Franz A. Mautner; Ramon Vicente; August A. Gallo; Elodie Ducasse
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 318 KB
- Volume
- 2007
- Category
- Article
- ISSN
- 1434-1948
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## Abstract Three azido‐bridged Mn^II^ complexes of formulas [Mn~2~(N~3~)~4~(ttp)~2~] (1), [Mn~2~(N~3~)~4~(ttp‐N~3~)~2~] (2) and [Mn~2~(N~3~)~4~(ttp‐N~3~)~2~]~3~[Mn^III^(ttp‐N~3~)(N~3~)~3~]~2~ (3), where ttp and ttp‐N~3~ represent 4′‐__p__‐tolyl‐2,2′:6′,2″‐terpyridine and 4′‐__p__‐azidomethylphenyl
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