Chiral racemic rhenium thiolate complexes [CpRe-SCH 2 CH 2 NHAc (8), SCH 2 CH 2 C(O)OH (9). A milder synthesis using hydrated sodium carbonate as a base (NO)(PPh 3 )(SR)] were obtained under either acidic or basic conditions. Thus, when [CpRe(NO)(PPh 3 )(CH 3 )] (1) was provided 8 and compounds with
Synthesis and Properties of Chiral Ruthenium Complexes Containing O-, S- and P-Functionalized Cp-Ligands
✍ Scribed by Adolphus A. H. van der Zeijden; Jhonny Jimenez; Chris Mattheis; Christoph Wagner; Kurt Merzweiler
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 599 KB
- Volume
- 1999
- Category
- Article
- ISSN
- 1434-1948
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract The coordination chemistry of Ru^II^ ions with [2‐(diphenylphosphanyl)‐__N__‐(__o__‐hydroxybenzylidene)]aniline (PNO‐H) and the methylated analogue PNO‐Me have been studied. Thus, [(PNO)RuCl(dmso)~2~] (1), [(PNO)~2~Ru] (2), [(PNO)RuCl(PPh~3~)] (3) and [(PNO)RuCl(CO)~2~] (4) were synthes
## Abstract The synthesis of a number of new 2,2′‐bipyridine ligands functionalized with bulky amino side groups is reported. Three homoleptic polypyridyl ruthenium (II) complexes, [Ru(L)~3~]^2+^ 2(PF~6~^−^), where L is 4,4′‐dioctylaminomethyl‐2,2′‐bipyridine (Ru4a), 4,4′‐didodecylaminomethyl‐2,2′‐