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Synthesis and Properties of Chiral N,N-Maleoyl Derivatives and Diels—Alder Reactions with Cyclopentadiene.

✍ Scribed by A. Bodtke; H.-H. Otto

Publisher
John Wiley and Sons
Year
2006
Weight
16 KB
Volume
37
Category
Article
ISSN
0931-7597

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✍ Yin Zhu; Xiaohong Chen; Mingsheng Xie; Shunxi Dong; Zhen Qiao; Dr. Lili Lin; Dr. 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 328 KB 👁 1 views

## Abstract Highly enantioselective Diels–Alder (DA) and inverse‐electron‐demand hetero‐Diels–Alder (HDA) reactions of β,γ‐unsaturated α‐ketoesters with cyclopentadiene catalyzed by chiral __N__,__N′__‐dioxide–Cu(OTf)~2~ (Tf=triflate) complexes have been developed. Quantitative conversion of β,γ‐un