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Lanthanide(III)-Catalyzed Multicomponent Aza-Diels—Alder Reaction of Aliphatic N-Arylaldimines with Cyclopentadiene.

✍ Scribed by David A. Powell; Robert A. Batey


Publisher
John Wiley and Sons
Year
2004
Weight
211 KB
Volume
35
Category
Article
ISSN
0931-7597

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## Abstract Highly enantioselective Diels–Alder (DA) and inverse‐electron‐demand hetero‐Diels–Alder (HDA) reactions of β,γ‐unsaturated α‐ketoesters with cyclopentadiene catalyzed by chiral __N__,__N′__‐dioxide–Cu(OTf)~2~ (Tf=triflate) complexes have been developed. Quantitative conversion of β,γ‐un