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Synthesis and Properties of Chelating N-Heterocyclic Carbene Rhodium(I) Complexes: Synthetic Experiments in Current Organometallic Chemistry

✍ Scribed by Mata, Jose A.; Poyatos, Macarena; Mas-Marzá, Elena


Book ID
120351151
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
741 KB
Volume
88
Category
Article
ISSN
0021-9584

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## Abstract Mixed N‐heterocyclic carbene‐substituted phosphine and phosphite complexes of rhodium were prepared, starting from [Rh(COE)~2~Cl]~2~ (COE=cyclooctene) by addition of free N‐heterocyclic carbenes (NHC) and PR~3~. All new complexes were characterized by spectroscopy. In addition, the stru