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Synthesis and characterization of chiral mono N-heterocyclic carbene-substituted rhodium complexes and their catalytic properties in hydrosilylation reactions

✍ Scribed by Martin Steinbeck; Guido D. Frey; Wolfgang W. Schoeller; Wolfgang A. Herrmann


Book ID
116680079
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
414 KB
Volume
696
Category
Article
ISSN
0022-328X

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## Abstract Mixed N‐heterocyclic carbene‐substituted phosphine and phosphite complexes of rhodium were prepared, starting from [Rh(COE)~2~Cl]~2~ (COE=cyclooctene) by addition of free N‐heterocyclic carbenes (NHC) and PR~3~. All new complexes were characterized by spectroscopy. In addition, the stru